Topochemical control in desolvation of coordination polymers
نویسنده
چکیده
Reactions in the solid state are at the core of crystal engineering as they can result in new crystalline phases that are not always accessible by traditional solution methods. The work of Brammer and co-workers [Wright et al. (2015), IUCrJ, 2, 188-197] represents a clear example of this potential as applied to the synthesis of a silver-phenazine coordination polymer.
منابع مشابه
Guest-induced crystal-to-crystal expansion and contraction of a 3-D porous coordination polymer.
A silver(I) 3-D porous coordination polymer (PCP, 1) with a sodalite topology undergoes a remarkable reversible crystal-to-crystal expansion and contraction upon exposure to different solvents. Notably, complete desolvation of 1 also facilitates a transformation to a non-porous 2-D coordination polymer (2).
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